NMR evaluation of the configurational stability of Cu(I) complexes |
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| Authors: | Desvergnes-Breuil Valérie Hebbe Virginie Dietrich-Buchecker Christiane Sauvage Jean-Pierre Lacour Jérôme |
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| Affiliation: | Département de Chimie Organique, Université de Genève, quai Ernest-Ansermet 30, CH-1211 Genève 4, Switzerland. |
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| Abstract: | Association of chiral [CuL2]+ complexes (L = 2-R-phen, 6-R-bpy, and 2-iminopyridine) with TRISPHAT (tris(tetrachlorobenzenediolato)phosphate(V)) anion leads to NMR enantiodifferentiation, which can be used to determine the kinetics of racemization of the complexes. |
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