The first structurally characterized nonorganometallic titanium(III) alkoxo-bridged dinuclear complexes |
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| Authors: | Utko Józef Przybylak Szymon Jerzykiewicz Lucjan B Mierzwicki Krzysztof Latajka Zdzisław Sobota Piotr |
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| Affiliation: | Faculty of Chemistry, University of Wroc?aw, 14, F. Joliot-Curie, 50-383 Wroc?aw, Poland. |
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| Abstract: | The reaction of [Ti4(OMe)14Cl2] (1) with an excess of AlMe3 gave the cocrystallite [Ti2(mu-OMe)2(mu-Cl)Cl3(thf)3].[Ti2(mu-OMe)3Cl3(thf)3] (2.3) species in a 1:1 ratio. Similar to 2, [Ti2(mu-OEt)2(mu-Cl)Cl3-(thf)3] (4) was obtained in the reaction of an equimolar mixture of TiCl4 and Ti(OEt)4 with Al/AlMe3. The short distance [2.543(1)av A in 2.3 and 2.599(1) A in 4] between "Ti(+3)" atoms, their diamagnetism, and ELF analysis indicate the presence of a Ti-Ti bond. |
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