Esterification in solution. The reaction of methacrylic acid with glycols |
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| Authors: | B I Charelishvili A A Berlin G V Lyubimova and M N Gusev |
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| Institution: | (1) Institute of Chemical Physics, Moscow, USSR |
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| Abstract: | Azeotropic methacrylation of ethylene glycols in solution in the presence of p-toluenesulfonic acid can be described by two irreversible consecutive-competitive second order reactions with a rate constant ratio of to 2. The main reaction may be complicated by esterification of p-toluenesulfonic acid. Under certain conditions this side reaction may become predominant. A possible reason of this phenomenon is suggested.
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