Kinetic model ofCO oxidation on a nonuniform surface analyzed with regard toCOads spillover, III. Homotopic method. Effect of the reaction mixture composition |
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| Authors: | E A Ivanov V I Savchenko and S I Fadeev |
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| Institution: | (1) Federal Scientific Centre  Boreskov Institute of Catalysis , Novosibirsk, Russia;(2) Sobolev Institute of Mathematics, 630090 Novosibirsk, Russia |
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| Abstract: | Homotopic method has been used to analyze the kinetic model of three-stageCO oxidation on two nonuniform surface patches conjugated byCO
ads spillover. The diagrams of steady states depending onP(CO) at various temperatures have been built.CO
ads spillover from one patch to another changes substantially the bifurcation picture of the steady states. |
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| Keywords: | Heterophase catalysis CO oxidation three-stage mechanism spillover homotopic method |
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