Synthesis of new trans-1,2-disilylethylene derivatives by hydrosilylation of ethynylsilanes |
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Authors: | M G Voronkov L V Shchukina O G Yarosh E O Tsetlina |
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Institution: | (1) Irkutsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, USSR |
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Abstract: | Conclusions Eight new trans-1,2-disilylethylenes were synthesized by the hydrosilylation of (CH C)2Si(OCH3)CH3 with HSiCl3 and HSi(CH3)Cl2, and also of (CH3)3SiC CH, CH3O(CH3)2SiC CH, and CH3(CH3O)2SiC CH with HSi(CH3)(C6H5)Cl9 and of (CH3O)3SiC CH with HSi(CH3)Cl2. The alcoholysis of these compounds with MeOH gave the corresponding methoxy derivatives.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1874–1877, August, 1976. |
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