Chemistry of Tetradentate [C,N : C,N] Iminophosphorane Palladacycles: Preparation,Reactivity and Theoretical Calculations |
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| Authors: | Dr Paula Munín-Cruz Francisco Reigosa Marcos Rúa-Sueiro Dr Juan M Ortigueira Prof M Teresa Pereira Prof José M Vila |
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| Institution: | Departamento de Química Inorgánica, Universidad de Santiago de Compostela, 15782 Santiago de Compostela, Spain |
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| Abstract: | A theoretical and experimental study of tetradentate C,N : C,N] iminophosphorane palladacycles was carried out for the purpose of elucidating their behavior as compared to the parent Schiff base analogues to determine the prospect of encountering new A-frame structures for the iminophosphorane derivatives. The DFT calculations were in agreement with the experimental results regarding the performance of these ligands. New insights into the chemistry of the related dinuclear species have been obtained. |
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| Keywords: | palladium diphosphine azides iminophosphorane density functional theory |
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