Über die Reaktivität des Schwefeldioxid-Radikalanions gegenüber reduzierbaren Substraten |
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Authors: | Dierk Knittel |
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Institution: | (1) Institut für Physikalische Chemie, Universität Hamburg, D-2000 Hamburg 13, Bundesrepublik Deutschland |
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Abstract: | A survey of reactions of the electrolytically prepared sulfurdioxide anion radical with various substrates containing reducible groups under aprotic and slightly protic conditions is presented. Beyond known reactions with mono-, vicinal and 1, -dihalides only -halogencarbonyl-, polyhalide-, nitro- and nitrosocompounds are reducible by this reagent. Aldehydes and carboxylic acid halides react but retain their state of oxidation. Anhydrides, esters and ketones are almost inert. Mechanisms are discussed and the scope for the use of S2O
4
–
as a nucleophile for the synthesis of sulfones and as a reducing agent is defined. |
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Keywords: | Sulfurdioxide anion radical Homogeneous reduction Hydroxy-methanesulfonates Hydroxylamino-N-sulfonates |
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