ESR study of radicals obtained from vinylalkoxysilanes and their adducts with branched fluoroalkenes |
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| Authors: | B L Tumanskii N A Chernyavskaya |
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| Institution: | (1) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813 Moscow, Russian Federation |
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| Abstract: | ESR spectra of radicals obtained by abstracting a hydrogen atom from methylvinyldimethoxysilane and methylvinyldiethoxysilane through the action of thetert-butoxy radical were studied. It was shown that the radicals appearing react with branched fluorinated olefins to give relatively stable radical adducts.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 538–540, March, 1994. |
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| Keywords: | vinylalkoxysilanes fluoroalkene radical ESR |
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