On the definition of the excess permittivity of a fluid mixture. II |
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Authors: | TP Iglesias Joo Carlos R Reis L Faria-Busto |
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Institution: | aDepartamento de Física Aplicada, Facultad de Ciencias, Universidad de Vigo, 36200 Vigo, Spain;bDepartamento de Química e Bioquímica, Centro de Ciências Moleculares e Materiais, Faculdade de Ciências, Universidade de Lisboa, 1749-016 Lisboa, Portugal |
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Abstract: | In a previous work, an ideal fluid mixture is assumed to be a homogeneous linear and isotropic system that verifies the following conditions: (I) no interaction between molecules, (II) point-like molecules and (III) under fixed temperature and pressure conditions the number of molecules per unit volume is the same for both the individual components and the mixture. It was shown that for such ideal mixture the permittivity is the sum of the individual permittivities weighted with the mole fractions of the components.In this work it is shown that independently of the latter assumption the permittivity of the system can be expressed as the sum of the individual permittivities weighted with the volume fractions of the components. |
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Keywords: | Excess permittivity Theoretical models Fluid mixtures |
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