| 酞菁配合物对锂-亚硫酰氯电池正极的催化作用 |
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| 引用本文： | 许占位,孙庆津,苏碧云,车兔林,宋艳虹,李要民,赵建社. 酞菁配合物对锂-亚硫酰氯电池正极的催化作用[J]. 电化学, 2007, 13(3): 293-296 |
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| 作者姓名： | 许占位 孙庆津 苏碧云 车兔林 宋艳虹 李要民 赵建社 |
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| 作者单位： | 西北大学化学系,陕西省物理无机化学重点实验室,陕西,西安,710069;西安机电信息研究所,陕西,西安,710065 |
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| 基金项目： | 国家自然科学基金(No.20671076)资助 |
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| 摘 要： | 合成过渡金属酞菁配合物MPc(M=Mn(Ⅱ),Fe(Ⅱ),Co(Ⅱ),N i(Ⅱ),Cu(Ⅱ)),研究MPc及其中心离子对L i/SOC l2电池正极的催化作用,并提出相关催化机理.
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| 关 键 词： | 过渡金属 酞菁配合物 锂/亚硫酰氯(Li/SOCl2) 催化机理 |
| 文章编号： | 1006-3471（2007）03-0293-04 |
| 收稿时间： | 2007-03-08 |
| 修稿时间： | 2007-04-27 |
Studies on Catalytic Mechanism of Li/SOCl2 Batteries by Metal Phthalocyanine Complexes |
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| XU Zhan-wei,SUN Qing-jin,SU Bi-yun,CHE Tu-lin,SONG Yan-hong,LI Yao-min,ZHAO Jian-she. Studies on Catalytic Mechanism of Li/SOCl2 Batteries by Metal Phthalocyanine Complexes[J]. Electrochemistry, 2007, 13(3): 293-296 |
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| Authors: | XU Zhan-wei SUN Qing-jin SU Bi-yun CHE Tu-lin SONG Yan-hong LI Yao-min ZHAO Jian-she |
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| Abstract: | Effects of metal phthalocyanine comlexes MPc(M= Mn(Ⅱ),Fe(Ⅱ),Co(Ⅱ),Ni(Ⅱ),Cu(Ⅱ)) as electrochemical catalysts on the performance of Li/SOCl2 batteries have been examined at constant resistance.And the reasons of MPc affecting the discharged voltage and discharged time of Li/SOCl2 batteries were also brought forward.A few new viewpoints on the catalytic mechanism of the reduction of thionyl chloride by phthalocyanine complexes were proposed. |
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| Keywords: | transition metal phthalocyanine complexes lithium/thionyl chloride catalytic mechanism |
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