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酞菁配合物对锂-亚硫酰氯电池正极的催化作用
引用本文:许占位,孙庆津,苏碧云,车兔林,宋艳虹,李要民,赵建社. 酞菁配合物对锂-亚硫酰氯电池正极的催化作用[J]. 电化学, 2007, 13(3): 293-296
作者姓名:许占位  孙庆津  苏碧云  车兔林  宋艳虹  李要民  赵建社
作者单位:西北大学化学系,陕西省物理无机化学重点实验室,陕西,西安,710069;西安机电信息研究所,陕西,西安,710065
基金项目:国家自然科学基金(No.20671076)资助
摘    要:合成过渡金属酞菁配合物MPc(M=Mn(Ⅱ),Fe(Ⅱ),Co(Ⅱ),N i(Ⅱ),Cu(Ⅱ)),研究MPc及其中心离子对L i/SOC l2电池正极的催化作用,并提出相关催化机理.

关 键 词:过渡金属  酞菁配合物  锂/亚硫酰氯(Li/SOCl2)  催化机理
文章编号:1006-3471(2007)03-0293-04
收稿时间:2007-03-08
修稿时间:2007-04-27

Studies on Catalytic Mechanism of Li/SOCl2 Batteries by Metal Phthalocyanine Complexes
XU Zhan-wei,SUN Qing-jin,SU Bi-yun,CHE Tu-lin,SONG Yan-hong,LI Yao-min,ZHAO Jian-she. Studies on Catalytic Mechanism of Li/SOCl2 Batteries by Metal Phthalocyanine Complexes[J]. Electrochemistry, 2007, 13(3): 293-296
Authors:XU Zhan-wei  SUN Qing-jin  SU Bi-yun  CHE Tu-lin  SONG Yan-hong  LI Yao-min  ZHAO Jian-she
Abstract:Effects of metal phthalocyanine comlexes MPc(M= Mn(Ⅱ),Fe(Ⅱ),Co(Ⅱ),Ni(Ⅱ),Cu(Ⅱ)) as electrochemical catalysts on the performance of Li/SOCl2 batteries have been examined at constant resistance.And the reasons of MPc affecting the discharged voltage and discharged time of Li/SOCl2 batteries were also brought forward.A few new viewpoints on the catalytic mechanism of the reduction of thionyl chloride by phthalocyanine complexes were proposed.
Keywords:transition metal  phthalocyanine complexes  lithium/thionyl chloride  catalytic mechanism
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