Specific heat and related thermophysical properties of liquid Fe-Cu-Mo alloy |
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Authors: | Wang HaiPeng Luo BingChi Chang Jian Wei BingBo |
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Institution: | Department of Applied Physics, Northwestern Polytechnical University, Xi'an 710072, China |
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Abstract: | The specific heat and related thermophysical properties of liquid Fe77.5Cu13Mo9.5 monotectic alloy were investigated by an electromagnetic levitation drop calorimeter over a wide temperature range from 1482
to 1818 K. A maximum undercooling of 221 K (0.13 T
m) was achieved and the specific heat was determined as 44.71 J·mol−1·K−1. The excess specific heat, enthalpy change, entropy change and Gibbs free energy difference of this alloy were calculated
on the basis of experimental results. It was found that the calculated results by traditional estimating methods can only
describe the solidification process under low undercooling conditions. Only the experimental results can reflect the reality
under high undercooling conditions. Meanwhile, the thermal diffusivity, thermal conductivity, and sound speed were derived
from the present experimental results. Furthermore, the solidified microstructural morphology was examined, which consists
of (Fe) and (Cu) phases. The calculated interface energy was applied to exploring the correlation between competitive nucleation
and solidification microstructure within monotectic alloy.
Supported by the National Natural Science Foundation of China (Grant Nos. 50121101 and 50395105) and the Doctorate Foundation
of Northwestern Polytechnical University (Grant No. CX200420) |
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Keywords: | high undercooling specific heat monotectic alloy thermophysical property rapid solidification |
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