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含有联萘环结构的新型环氧树脂的合成与性能研究
引用本文:宣宜宁,刘伟区,陈精华. 含有联萘环结构的新型环氧树脂的合成与性能研究[J]. 广州化学, 2003, 28(4): 1-5
作者姓名:宣宜宁  刘伟区  陈精华
作者单位:中国科学院,广州化学研究所,广东,广州,510650
摘    要:以2-萘酚为原料,先合成出2,2?二羟基-1,1?联萘,再合成出一种新型的具有联萘结构的环氧树脂(BEBN)。通过红外光谱研究了树脂的结构,推测了树脂合成的机理,并对树脂的性能作了一定的研究。该树脂的固化物表现出良好的热性能及力学性能。

关 键 词:环氧树脂  联萘基团  合成  热性能
文章编号:1009-220X(2003)04-0001-05
修稿时间:2003-07-15

Synthesis and Properties of a Novel Epoxy Resin Containing 1,1''''-Binaphthalene Moiety
XUAN Yi-ning,LIU Wei-qu,CHEN Jing-hua. Synthesis and Properties of a Novel Epoxy Resin Containing 1,1''''-Binaphthalene Moiety[J]. Guangzhou Chemistry, 2003, 28(4): 1-5
Authors:XUAN Yi-ning  LIU Wei-qu  CHEN Jing-hua
Abstract:A novel epoxy resin containing 1,1?binaphthalene moiety was synthesized by the reaction of epichlorohydrin with 2,2'-dihydroxy-1,1'-binaphthalene,which was obtained via oxidative coupling of 2-naphthol. The molecular structure and the mechanism for the reaction were analyzed by FT-IR spectra. The properties of the polymer were studied. The cured resin shows good thermal and mechanical properties.
Keywords:epoxy resins  binaphthalene unit  synthesis  thermal property  
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