| 硝基基团修饰的金属有机框架化合物的合成及晶体结构表征 |
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| 引用本文： | 李崧,邓临新,何俊杰,刘辉,曾和平.硝基基团修饰的金属有机框架化合物的合成及晶体结构表征[J].无机化学学报,2014,30(10):2401-2407. |
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| 作者姓名： | 李崧 邓临新 何俊杰 刘辉 曾和平 |
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| 作者单位： | 1. 华南理工大学化学与化工学院,广东省燃料电池技术重点实验室,广州 510640
2. 云南警官学院,昆明,650221 |
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| 基金项目： | 国家自然科学基金（No.21371060），中国博士后科学基金（No.2012M510198）资助项目。 |
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| 摘 要： | 分别以2种硝基羧酸配体EBNB(1,2-二(3-硝基苯甲酸)-乙烯)和NPA(3-硝基邻苯二甲酸)与BPY(4,4′-联吡啶)及金属锌反应,配位溶剂热法合成了2种具有硝基基团修饰的二核金属簇为基本构筑单元的金属有机框架化合物Zn2(EBNB)2(BPY)2·2H2O]n(1)和Zn2(NPA)2(BPY)2·H2O]n(2)。通过X-射线单晶衍射法测定了2种配合物的结构,其中配合物1属于三斜晶系,P1空间群,a=0.818 62(9)nm,b=1.142 20(14)nm,c=1.428 63(17)nm,α=96.803 0(10)°,β=93.045 0(10)°,γ=102.472(2)°,V=1.290 8(3)nm3,Z=2,Mr=595.81,Dc=1.533 g·cm-3,μ=1.01 mm-1,F(000)=608,T=293(2)K;配合物2属于三斜晶系,P1空间群,a=1.154 06(14)nm,b=1.190 86(16)nm,c=1.459 52(19)nm,α=98.029(1)°,β=98.749(1)°,γ=113.579(2)°,V=1.771 9(4)nm3,Z=2,Mr=879.35,Dc=1.648 g·cm-3,μ=1.43 mm-1,F(000)=892,T=293(2)K。同时也对2种配合物的发光性能进行了测试,测试结果表明2种配合物具有较好的荧光性能。
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| 关 键 词： | 金属有机框架 穿插结构 基本构筑单元 硝基基团 修饰 |
| 收稿时间： | 2014/1/17 0:00:00 |
| 修稿时间： | 2014/5/18 0:00:00 |
Synthesis and Characterization of Two Metal-Organic Frameworks (MOFs) with Nitro Group Functionalization Ligands |
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| LI Song,DENG Lin-Xin,HE Jun-Jie,LIU Hui and ZENG He-Ping.Synthesis and Characterization of Two Metal-Organic Frameworks (MOFs) with Nitro Group Functionalization Ligands[J].Chinese Journal of Inorganic Chemistry,2014,30(10):2401-2407. |
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| Authors: | LI Song DENG Lin-Xin HE Jun-Jie LIU Hui and ZENG He-Ping |
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| Institution: | Key Laboratory of Fuel Cell Technology of Guangdong Province, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China;Yunnan Police Officer Academy, Kunming 650221, China;Key Laboratory of Fuel Cell Technology of Guangdong Province, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China;Key Laboratory of Fuel Cell Technology of Guangdong Province, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China;Key Laboratory of Fuel Cell Technology of Guangdong Province, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China |
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| Abstract: | |
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| Keywords: | metal-organic framework interpenetrated secondly building unit nitro group modification |
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