Migration of an acetyl group in glucosamine and glucose derivatives by the action of butyllithium. The synthesis of an N-acetylglucosamine 4-phosphate derivative |
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Authors: | V I Gorbach I N Krasikova P A Luk'yanov T F Solov'eva Yu S Ovodov |
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Institution: | (1) Pacific Ocean Institute of Bioorganic Chemistry, Far East Science Center, Academy of Sciences of the USSR, Vladivostok |
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Abstract: | Conclusions The migration of the acetyl group from C4 to C6 occurs in partially acetylated derivatives of D-glucose and D-glucosamine upon reaction with butyllithium.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2106-2109, September, 1987. |
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