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(Chloromethyl)pentacarbonylmanganese(I): a crystal structure with a non-crystallographic centre of symmetry |
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| Authors: | Brian K Nicholson J Scott McIndoe Dore Augusto Clemente Ward T Robinson |
| Institution: | (1) Chemistry Department, University of Waikato, Private Bag 3105, Hamilton, 3240, New Zealand;(2) Department of Chemistry, University of Victoria, P.O. Box 3065, Victoria, BC, Canada, V8W 3V6;(3) Department of Materials and Natural Resources, Applied Chemistry Division, University of Trieste at Pordenone, Via Prasecco 31A, 33170 Pordenone, Italy;(4) Chemistry Department, University of Canterbury, Private Bag 4800, Christchurch, New Zealand |
| Abstract: | There are two molecules in the asymmetric unit of the P21/c unit cell of ClCH2Mn(CO)5, the first halomethyl complex of manganese to be structurally determined. The molecules are crystallographically independent, despite an apparent local centre of symmetry. The average bond parameters include Mn–Calkyl 2.128(8) Å, C–Cl 1.811(8) Å and Mn–C–Cl 116.4(4)°. |
| Keywords: | Chloromethyl Manganese carbonyl Crystal structure Non-crystallographic symmetry |
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