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Determination of the interaction enthalpy between microemulsion droplets by isothermal titration microcalorimetry
Authors:Zheng Peizhu  Ma Yuanming  Peng Xuhong  Yin Tianxiang  An Xueqin  Shen Weiguo
Institution:School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, China.
Abstract:A new experimental design for the measurement of the real heat of dilution of the microemulsion droplets by isothermal titration microcalorimetry (ITC) has been reported and used to study the interaction enthalpies of the droplets for the system of water/sodium bis(2-ethylhexyl)-sulfosuccinate (AOT)/toluene. The results are in good agreement with those determined from light-scattering experiments.
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