UV-Vis Spectrum and the Third-order Nonlinear Optical Properties of the Chiral Camphorderived β-diketonate Platinum Complexes |
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作者姓名: | GONG Xue WEI Hang LUO Kai-Jun LI Quan② |
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基金项目: | Project supported by the National Natural Science Foundation of China (21172161 ) |
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摘 要: | UV-Vis spectrum and the third-order nonlinear optical properties of the chiral camphor-derived β-diketonate have been studied at the B3LYP/6-31G* level. The results showed that the introduction of electron-drawing group-CF3 and-C3F7 on β-diketonate made the strongest absorption peak red-shift and the lowest energy absorption blue-shied. Introduction of-OC2H5 on the benzene or pyridine ring made the lowest energy absorption blue-shift. When the-C2H3 was introduced on the benzene or pyridine ring, the lowest energy absorption was red-shifted. Introduction of electron-donating group on β-diketonate can enlarge their nonlinear optical properties. On the contrary, the introduction of electron-drawing group dropped it down.
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关 键 词: | camphor-derived β-diketonate platinum complexes the third-order nonlinear optical properties UV-Vis absorption spectrum density functional theory |
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