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Cation → anion energy transfer in [Cr(en)3][Cr(CN)6]·2H2O |
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| Authors: | Francesco Castelli Leslie S. Forster |
| Affiliation: | Department of Chemistry, University of Arizona, Tucson, Arizona 85721, USA |
| Abstract: | Energy transfer from Cr(en)33+ to Cr(CN)63− has been observed in [Cr(en)3][Cr(CN)6]·2H2O with an efficiency close to unity. The 4T2 & rt arrow-wavy; 2E intersystem crossing efficiency in Cr(en)33+ is also unity. |
| Keywords: | en = ethylenedianine atp = antipyrine bipy = 2 2′-bipyridine |
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