Investigating Electronic Communications in meso–meso Ethene-Bridged Unsymmetrical Diporphyrins |
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| Authors: | Anna Zieleniewska Prof?Dr Dirk M Guldi |
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| Institution: | Department of Chemistry and Pharmacy, Friedrich-Alexander-University Erlangen-Nürnberg, 91058 Erlangen, Germany |
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| Abstract: | At the focal point of this work is the photophysical characterization of three meso–meso ethene-bridged diporphyrins featuring a diverse metallation pattern. Detailed investigations by means of cyclic voltammetry, absorption, fluorescence, and femto-/nanosecond transient absorption spectroscopy revealed the impact of open-shell nickel(II) on the electronic communication in ethene-bridged heterobimetallic diporphyrins. |
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| Keywords: | diporphyrins electronic communication photochemistry porphyrin dimers porphyrinoids |
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