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When a Red–NIR-Emissive Cs2[Mo6Br14] Interacts with an Active Diureasil–PEO Matrix: Design of Tunable and White-Light-Emitting Hybrid Material |
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| Authors: | Dr Eduardo Ferreira Molina Natana Aparecida Martins de Jesus Serge Paofai Dr Peter Hammer Dr Maria Amela-Cortes Dr Malo Robin Dr Stephane Cordier Dr Yann Molard |
| Institution: | 1. Universidade de Franca, Av. Dr. Armando Salles Oliveira 201, 14404-600 Franca, SP Brazil;2. Univ Rennes, CNRS, ISCR-UMR 6226, ScanMAT-UMS 2001, 35000 Rennes, France;3. Instituto de Quimica, UNESP-Universidade Estadual Paulista, 4800-900 Araraquara, SP Brazil |
| Abstract: | Hybrid materials that combine diureasil matrices and octahedral molybdenum clusters have been synthesized to design lead-, cadmium- and rare-earth-free emitters for lighting or optoelectronic applications. This association leads to homogeneous and stable hybrids, for which the emission color can be tailored in the entire visible range, including white light; this is thanks to effective energy transfers from the host to the nanocluster. |
| Keywords: | energy transfers hybrid materials luminescence metal clusters |