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N-Boc-Amides in Cross-Coupling Reactions
Authors:Yann Bourne-Branchu  Dr. Corinne Gosmini  Dr. Grégory Danoun
Affiliation:LCM, CNRS, Ecole Polytechnique, Université Paris-Saclay, 91128 Palaiseau Cedex, France
Abstract:Since 2015, the use of amides as electrophilic partners in cross-coupling reactions has experienced exponential growth. Diverse amide derivatives have been studied and among them N-Boc-amides have shown good activities towards various cross-coupling reactions and presents, in our view, an important synthetic usefulness. This review describes the recent developments of these chemical transformations involving N-Boc-amides.
Keywords:amides  Boc activation  C−N activation  cross-coupling  homogeneous catalysis
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