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Comparing the Self-Assembly of Sexiphenyl-Dicarbonitrile on Graphite and Graphene on Cu(111)
Authors:Nico Schmidt  Dr. Jun Li  Dr. Stefano Gottardi  Dr. Juan Carlos Moreno-Lopez  Dr. Mihaela Enache  Dr. Leticia Monjas  Ramon van der Vlag  Dr. Remco W. A. Havenith  Prof. Dr. Anna K. H. Hirsch  Prof. Dr. Meike Stöhr
Affiliation:1. Zernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, 9747 AG, Groningen, The Netherlands;2. Zernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, 9747 AG, Groningen, The Netherlands

Current affiliation: Faculty of Physics, University of Vienna, Strudlhofgasse 4, 1090 Vienna, Austria;3. Stratingh Institute for Chemistry, University of Groningen, Nijenborgh 7, 9747 AG, Groningen, The Netherlands;4. Zernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, 9747 AG, Groningen, The Netherlands

Stratingh Institute for Chemistry, University of Groningen, Nijenborgh 7, 9747 AG, Groningen, The Netherlands

Ghent Quantum Chemistry Group, Department of Inorganic and Physical Chemistry, Ghent University, Krijgslaan 281 (S3), 9000 Ghent, Belgium

Abstract:A comparative study on the self-assembly of sexiphenyl-dicarbonitrile on highly oriented pyrolytic graphite and single-layer graphene on Cu(111) is presented. Despite an overall low molecule–substrate interaction, the close-packed structures exhibit a peculiar shift repeating every four to five molecules. This shift has hitherto not been reported for similar systems and is hence a unique feature induced by the graphitic substrates.
Keywords:graphene  nanostructures  scanning probe microscopy  self-assembly  surface analysis
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