Synthesis and Thermal Decomposition of Heavy Tetrylenes Bearing N-Aminocarbazolyl Substituents |
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| Authors: | Dr Alexander Hinz |
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| Institution: | Institute of Inorganic Chemistry (AOC), Karlsruhe Institute of Technology (KIT), Engesserstr. 15, Gebäude 30.45, 76131 Karlsruhe, Germany |
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| Abstract: | The synthesis of the N-aminocarbazole R-NH2 ( 2 ) is reported. Subsequent reaction with bisbis(trimethylsilyl)amido]tetrylenes EN(SiMe3)2]2 (E=Ge, Sn, or Pb) allowed the isolation of formal hydrazidotetrylene derivatives, R?N(H)EN(SiMe3)2 ( 3 ) that includes the first example of a hydrazidoplumbylene to date. Thermal decomposition of these compounds resulted in the elimination of “NH” and afforded the tetrylenes R-EN(SiMe3)2 ( 4 ). |
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| Keywords: | amides germanium lead steric hindrance tin |
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