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Oxo-Thiolation of Cationically Polymerizable Alkenes Using Flow Microreactors |
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| Authors: | Dr Yosuke Ashikari Dr Kodai Saito Prof Dr Toshiki Nokami Prof Dr Jun-ichi Yoshida Prof Dr Aiichiro Nagaki |
| Institution: | 1. Department of Synthetic and Biological Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto, 615-8510 Japan;2. Department of Chemistry, Keio University, 3-14-1 Hiyoshi, Kohoku-ku, Yokohama, 223-8522 Japan;3. Department of Chemistry and Biotechnology and Center for Research on Green Sustainable Chemistry, Graduate School of Engineering, Tottori University, 4-101 Koyama-minami, Tottori, 680-8552 Japan;4. National Institute of Technology, Suzuka College, Shiroko-cho, Suzuka, Mie, 510-0294 Japan |
| Abstract: | The present study describes the cationic oxo-thiolation of polymerizable alkenes by using highly reactive cationic species generated by anodic oxidation. These highly reactive cations were able to activate alkenes before their polymerization. Fast mixing in flow microreactors effectively controlled chemoselectivity, enabling higher reaction temperatures. |
| Keywords: | alkenes anodic oxidation cationics electrochemistry flow microreactors polymerization |