A Systematic Survey of the Reactivity of Chlorinated N2P2, NP3 and P4 Ring Systems |
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| Authors: | Dr Jonas Bresien Liesa Eickhoff Prof Dr Axel Schulz Tim Suhrbier Dr Alexander Villinger |
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| Institution: | Institut für Chemie, Universität Rostock, Albert-Einstein-Str. 3a, 18059 Rostock, Germany |
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| Abstract: | The reactivity of the four-membered NP3 ring system RN(μ-PCl)2PR] (R=Mes*=2,4,6-tri-tert-butylphenyl) towards Lewis acids, Lewis bases, and reducing agents was investigated. Comparisons with the literature-known, analogous cyclic compounds ClP(μ-NR)]2 (R=Ter=2,6-dimesitylphenyl) and ClP(μ-PR)]2 (R=Mes*) are drawn, to obtain a better systematic understanding of the reactivity of cyclic NP species. Apart from experimental results, DFT computations are discussed to further the insight into bonding and electronic structure of these compounds. |
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| Keywords: | biradicals computational chemistry phosphorus PN chemistry ring systems |
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