Metal-Organic Framework Derived Hierarchical Co/C@V2O3 Hollow Spheres as a Thin,Lightweight, and High-Efficiency Electromagnetic Wave Absorber |
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Authors: | Chenhui Zhou Prof. Chen Wu Dr. Dong Liu Prof. Mi Yan |
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Affiliation: | 1. School of Materials Science and Engineering, State Key Laboratory of Silicon Materials, Zhejiang University, Hangzhou, 310027 China;2. School of Chemistry and Materials Science, Ludong University, Yantai, 264025 China |
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Abstract: | Developing high-efficiency electromagnetic (EM) wave absorbing materials with light weight, thin thickness, and wide absorption bandwidth is highly desirable for ever-developing electronic and telecommunication devices. Herein, hierarchical metal–organic framework (MOF)-derived Co/C@V2O3 hollow spheres were designed and synthesized through a facile hydrothermal, precipitation, and pyrolysis method. The composite exhibits both excellent impedance matching and light weight due to the rational combination of hollow V2O3 spheres and porous Co/C. Additionally, multiple components enable a large dielectric and magnetic loss of the composite, giving rise to enhanced EM wave absorption performance with a maximum reflection loss (RL) of −40.1 dB and a broad effective absorption bandwidth (RL < −10 dB) of 4.64 GHz at a small thickness of 1.5 mm. This work provides insights into the design of hierarchical hollow and porous composites as thin and lightweight EM wave absorbers with efficient absorption, which can also be extended to energy storage, catalysis, and sensing. |
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Keywords: | Co/C@V2O3 composites dielectric/magnetic composites electromagnetic wave absorption hierarchical hollow spheres metal–organic framework |
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