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Generation and Reactivity of a One-Electron-Oxidized Manganese(V) Imido Complex with a Tetraamido Macrocyclic Ligand |
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| Authors: | Huatian Shi Jianhui Xie William W. Y. Lam Wai-Lun Man Chi-Keung Mak Shek-Man Yiu Hung Kay Lee Tai-Chu Lau |
| Affiliation: | 1. Department of Chemistry, City University of Hong Kong, Tat Chee Avenue, Kowloon Tong, Hong Kong SAR, P. R. China;2. School of Chemistry and Chemical Engineering, Hefei University of Technology, Hefei, 230009 P. R. China;3. Department of Food and Health Sciences, Technological and Higher Education Institute of Hong Kong, Tsing Yi Road, Hong Kong SAR, P. R. China;4. Department of Chemistry, Hong Kong Baptist University, Kowloon Tong, Hong Kong SAR, P. R. China;5. Department of Chemistry, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong SAR, P. R. China |
| Abstract: | The synthesis and X-ray structure of a new manganese(V) mesitylimido complex with a tetraamido macrocyclic ligand (TAML), [MnV(TAML)(N-Mes)]− ( 1 ), are reported. Compound 1 is oxidized by [(p-BrC6H4)3N ]+.[SbCl6]− and the resulting MnVI species readily undergoes H-atom transfer and nitrene transfer reactions. |
| Keywords: | coordination chemistry hydrogen atom transfer imido transfer one-electron oxidation manganese |