Dehydrogenation of Amine–Boranes Using p-Block Compounds |
| |
Authors: | Dr Devin H A Boom Dr Andrew R Jupp Prof Dr J Chris Slootweg |
| |
Institution: | Van 't Hoff Institute for Molecular Sciences, University of Amsterdam, Science Park 904, 1090 GD Amsterdam, The Netherlands |
| |
Abstract: | Amine–boranes have gained a lot of attention due to their potential as hydrogen storage materials and their capacity to act as precursors for transfer hydrogenation. Therefore, a lot of effort has gone into the development of suitable transition- and main-group metal catalysts for the dehydrogenation of amine–boranes. During the past decade, new systems started to emerge solely based on p-block elements that promote the dehydrogenation of amine–boranes through hydrogen-transfer reactions, polymerization initiation, and main-group catalysis. In this review, we highlight the development of these p-block based systems for stoichiometric and catalytic amine–borane dehydrogenation and discuss the underlying mechanisms. |
| |
Keywords: | amine–boranes ammonia–borane dehydrogenation hydrogen transfer main-group catalysis |
|
|