| Syntheses，Structures and Spectroscopic Properties of Mo（W）－Cu－S－Cluster Compounds with Dialkyldithiocarbamate Ligands |
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| 引用本文： | Cao Rong,Lei Xin-Jian,Hong Mao-Chun,Xie Xiu-Lan,Kang Bei-Sheng,Jiang Fei-Long,Liu Qiu-Tian,Liu Han-Qin(State Key Labofratory of Structural Chemistry and Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou,Fujian 3500. Syntheses，Structures and Spectroscopic Properties of Mo（W）－Cu－S－Cluster Compounds with Dialkyldithiocarbamate Ligands[J]. 结构化学, 1995, 0(1) |
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| 作者姓名： | Cao Rong Lei Xin-Jian Hong Mao-Chun Xie Xiu-Lan Kang Bei-Sheng Jiang Fei-Long Liu Qiu-Tian Liu Han-Qin(State Key Labofratory of Structural Chemistry and Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou Fujian 3500 |
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| 作者单位： | State Key Labofratory of Structural Chemistry and Fujian Institute of Research on the Structure of Matter，Chinese Academy of Sciences，Fuzhou，Fujian 3500 |
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| 摘 要： | Ｓｙｎｔｈｅｓｅｓ，ＳｔｒｕｃｔｕｒｅｓａｎｄＳｐｅｃｔｒｏｓｃｏｐｉｃＰｒｏｐｅｒｔｉｅｓｏｆＭｏ（Ｗ）－Ｃｕ－Ｓ－ＣｌｕｓｔｅｒＣｏｍｐｏｕｎｄｓｗｉｔｈＤｉａｌｋｙｌｄｉｔｈｉｏｃａｒｂａｍａｔｅＬｉｇａｎｄｓＣａｏＲｏｎｇ；ＬｅｉＸｉｎ－Ｊｉ...
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Syntheses,Structures and Spectroscopic Properties of Mo(W)-Cu-S-Cluster Compounds with Dialkyldithiocarbamate Ligands |
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| Cao Rong,Lei Xin-Jian,Hong Mao-Chun,Xie Xiu-Lan,Kang Bei-Sheng,Jiang Fei-Long,Liu Qiu-Tian,Liu Han-Qin. Syntheses,Structures and Spectroscopic Properties of Mo(W)-Cu-S-Cluster Compounds with Dialkyldithiocarbamate Ligands[J]. Chinese Journal of Structural Chemistry, 1995, 0(1) |
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| Authors: | Cao Rong Lei Xin-Jian Hong Mao-Chun Xie Xiu-Lan Kang Bei-Sheng Jiang Fei-Long Liu Qiu-Tian Liu Han-Qin |
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| Abstract: | This paper presents the synthetic and structure studies of molybdenum(tungsten)-copper-sulphur-dialkyldithiocarbamate cluster compounds.The reactions of(M=Mo,W;n=0,2),CuCl,and R_2dtc￣-(R_2=Me_2,Et_2,C_4H_8,C_5H_10) yield a series of tetra-,hexa-,and heptanuclear cluster compounds.Their spectroscopic properties and the synthetic reaction mechanism are discussed. |
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| Keywords: | Mo(W)-Cu-S cluster compounds dialkyldithiocarbamate(R_2dtc) structures reaction mechanism |
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