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A new strategy for asymmetric synthesis of aminophosphonic acid derivatives: the first enantioselective catalytic reduction of C-phosphorylated imines |
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| Authors: | Yuliya V. Rassukana Mykola V. Kolotylo Piotr ?y?wa |
| Affiliation: | a Institute of Organic Chemistry, National Academy of Sciences, Kiev 02094, 5 Murmans’ka St, Ukraine b Centre of Molecular and Macromolecular Studies, Polish Academy of Sciences, 90-363 ?ód?, Sienkiewicza 112, Poland |
| Abstract: | The first highly enantioselective catalytic reduction of 1-imino-2,2,2-trifluoroethylphosphonates and the synthesis of enantiomerically enriched biorelevant phosphonotrifluoroalanine is reported. |
| Keywords: | Imidoyl phosphonates Aminophosphonic acids N-H imines Enantioselective synthesis Catalytic reduction |
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