| 稀土、2,2''''-联吡啶、邻氨基苯基苯甲酸配合物合成、光谱表征及荧光性质 |
| |
| 引用本文： | 王少亭,杨永丽,朱惠菊,聂峰梅,宗瑞发,邓玉恒. 稀土、2,2''''-联吡啶、邻氨基苯基苯甲酸配合物合成、光谱表征及荧光性质[J]. 光谱学与光谱分析, 2006, 26(5): 933-935 |
| |
| 作者姓名： | 王少亭 杨永丽 朱惠菊 聂峰梅 宗瑞发 邓玉恒 |
| |
| 作者单位： | 王少亭（首都师范大学化学系,北京,100037）;杨永丽（首都师范大学化学系,北京,100037）;朱惠菊（首都师范大学化学系,北京,100037）;聂峰梅（首都师范大学化学系,北京,100037）;宗瑞发（首都师范大学化学系,北京,100037）;邓玉恒（首都师范大学化学系,北京,100037） |
| |
| 基金项目： | 北京市科技新星计划项目 , 北京市教委科研项目 |
| |
| 摘 要： | 2,2'-联吡啶(bipy)、邻氨基苯基苯甲酸(HL)与稀土离子(RE=Tb,Eu,Sm,Nd)合成了固体稀土配合物.用元素分析、摩尔电导、紫外光谱、红外光谱、差热-热重分析和荧光光谱,对配合物的组成进行了确定和表征,并对TbL3和TbL3·bipy·3H2O的荧光性能进行了测试和讨论.TbL3·bipy·3H2O的荧光强度比TbL3的荧光强度强.
|
| 关 键 词： | 稀土配合物 2,2'-联吡啶 邻氨基苯基苯甲酸 荧光性质 |
| 文章编号： | 1000-0593（2006）05-0933-03 |
| 收稿时间： | 2005-09-22 |
| 修稿时间： | 2005-12-28 |
Synthesis and Spectral Characterization of Rare-Earth-Ortho-Amino Phenylbenzoate-2,2 ''''-Bipyridine Complexes |
| |
| WANG Shao-ting,YANG Yong-li,ZHU Hui-ju,NIE Feng-mei,ZONG Rui-fa,DENG Yu-heng. Synthesis and Spectral Characterization of Rare-Earth-Ortho-Amino Phenylbenzoate-2,2 ''''-Bipyridine Complexes[J]. Spectroscopy and Spectral Analysis, 2006, 26(5): 933-935 |
| |
| Authors: | WANG Shao-ting YANG Yong-li ZHU Hui-ju NIE Feng-mei ZONG Rui-fa DENG Yu-heng |
| |
| Affiliation: | Department of Chemistry, Capital Normal University, Beijing 100037, China. |
| |
| Abstract: | The solid rare-earth complexes were synthesized using rare-earth ions (RE=Tb, Nd, Sm, La) reacting with ortho-amino phenylbenzoic acid (L) and 2,2'-bipyridine (bipy). Their compositions were confirmed and the spectral properties were characterized by element analysis, infrared and ultraviolet absorption spectra, and DTA-TGA. The fluorescent properties of complexes TbL3 and TbL3 x bipy x 3H2O were also measured and discussed. The result shows that the fluorescence intensity of TbL3 x bipy 3H2O is stronger than that of TbL3. |
| |
| Keywords: | |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
|
