Stereoselective synthesis of 3,4-disubstituted tetrahydrofurans and 2,3,4-trisubstituted tetrahydrofurans using an intramolecular allylation strategy employing allylsilanes |
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| Authors: | Peter J Jervis |
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| Institution: | School of Chemistry, The University of Birmingham, Edgbaston, Birmingham B15 2TT, UK |
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| Abstract: | A Brønsted acid-mediated intramolecular allylation involving an allylsilane and an aldehyde has been used as the key step in a stereoselective synthesis of 3,4-disubstituted tetrahydrofurans and 2,3,4-trisubstituted tetrahydrofurans. |
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| Keywords: | Allylsilanes Tetrahydrofurans Cyclisation Intramolecular allylation Brø nsted acids |
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