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The conductivity of dilute aqueous solutions of magnesium chloride at 25°C
Authors:Hugo Bianchi  Horacio R. Corti  Roberto Fernandez-Prini
Affiliation:(1) Departamento Química de Reactores, Comisión Nacional de Energía Atómica, Av. Libertador 8250, 1429 Capital Federal, Argentina
Abstract:There is a disagreement in the literature regarding the best value of Lambdao[1/2MgCl2]. For this reason, the conductivity of dilute aqueous MgCl2 solutions have been determined at 25°C. The new experimental data and those available in the literature have been analyzed with two theoretical treatments of electrolytic conductivity. On the basis of that analysis, the values 129.72±0.05 and 53.40±0.05 S-cm2-mol–1 for Lambdao[1/2MgCl2] and lambdao[1/2Mg2+], respectively, are recommended.
Keywords:Electrolytic conductivity  aqueous solutions  ionic mobility  magnesium chloride
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