Ruthenium-catalyzed linear selective allylic aminations of monosubstituted allyl acetates |
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| Authors: | Motoi Kawatsura |
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| Institution: | Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University, Koyama, Tottori 680-8552, Japan |
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| Abstract: | The ruthenium-catalyzed highly linear selective allylic amination of monosubstituted allylic acetates with secondary amines was developed. The regioselectivity was controlled by the Ru3(CO)12/2-DPPBA catalyst, and a linear-type aminated product was obtained as a single regioisomer. |
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| Keywords: | Ruthenium Catalyst Allylic amination Regioselectivity |
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