Chiral azabicyclo-N-oxyls mediated enantioselective electrooxidation of sec-alcohols |
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| Authors: | Hirofumi Shiigi |
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| Institution: | Graduate School of Biomedical Sciences, Nagasaki University, 1-14 Bunkyo-machi, Nagasaki 852-8521, Japan |
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| Abstract: | Enantiomerically pure azabicyclo-N-oxyls were prepared from l-hydroxyproline. They mediated enantioselective electrooxidation of racemic sec-alcohols to afford optically active sec-alcohols with moderate to high s value (up to 21). |
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| Keywords: | Chiral nitroxyl radical Enantioselective oxidation Optically active alcohol Electrooxidation |
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