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A chiral Mn(III) salen complex immobilized onto ionic liquid modified mesoporous silica for oxidative kinetic resolution of secondary alcohols |
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| Authors: | Suman Sahoo F. Lefebvre |
| Affiliation: | a Inorganic Chemistry and Catalysis Division, National Chemical Laboratory, Pune 411 008, India b Organic Chemistry Technology, National Chemical Laboratory, Pune 411 008, India c Laboratoire de Chemie Organometallique de Surface, CNRS-CPE, Villeurbanne Cedex, France |
| Abstract: | A supported ionic liquid strategy has been applied for the immobilization of a chiral Mn(III) salen complex onto ionic liquid modified mesoporous silica SBA-15. The immobilized catalyst demonstrated high enantioselectivity and activity in the oxidative kinetic resolution of secondary alcohols, and could be recycled five times without obvious loss of activity. |
| Keywords: | Oxidative kinetic resolution Secondary alcohol Mn(III) salen Mesoporous silica SBA-15 Supported ionic liquid |
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