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Building addressable libraries: a site-selective allyl alkylation reaction
Authors:Jun Tian  Kevin D. Moeller
Affiliation:a Department of Chemistry, Washington University, St. Louis, MO 63130, United States
b CombiMatrix Corporation, 6500 Harbour Heights Pkwy, Suite 301, Mukilteo, WA 98275, United States
Abstract:A Pd(0) catalyst has been used to effect allyl alkylation reactions at pre-selected locations on an addressable microelectrode array. The reactions provide a new approach to site-selective carbon-carbon bond formation and a new method for placing substrates on the surface of a microelectrode array.
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