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Enantiospecific synthesis of (+)-hernandulcin
Authors:Francesco G. Gatti
Affiliation:Dipartimento di Chimica dei Materiali ed Ingegneria Chimica ‘G. Natta’ del Politecnico, Via Mancinelli 7, 20131 Milano, Italy
Abstract:The sesquiterpene (+)-hernandulcin has been enantiospecifically synthesized starting from (−)-neoisopulegol in seven steps and in 25% overall yield.
Keywords:Metalation   Sesquiterpene   Epoxidation   Sweetener   Enone
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