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Enantioselective rhodium(I)-triethylamine catalyzed addition of potassium isopropenyl trifluoroborate to enones
Authors:Gojko Lalic
Affiliation:Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, MA 02138, USA
Abstract:A general process is reported for the highly enantioselective 1,4-addition of isopropenyl trifluoroborate to cyclic enones under catalysis by a chiral Rh(I) complex and triethylamine at room temperature.
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