Anhydride-functionalized fullerene: a versatile precursor for fullerene-based materials |
| |
Authors: | Gyu Seong Heo |
| |
Institution: | Department of Chemistry, Sogang University, Seoul 121-742, Republic of Korea |
| |
Abstract: | Soluble phthalic anhydride-functionalized fullerene was generated via simple pyrolysis of the corresponding di-t-butyl phthalate precursor at 200 °C for 120 min. This non-chemical method for generating electrophilic fullerene may be advantageous for the preparation of various fullerene-containing materials. The utility of the resulting fullerene anhydride was demonstrated by solution coupling reaction with PEG-amine, surface reaction with amine-functionalized glass, and hydrolysis reaction to form amphiphilic fullerene. |
| |
Keywords: | Fullerenes Anhydrides Pyrolysis Phthalates |
本文献已被 ScienceDirect 等数据库收录! |