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Temperature induced rotation in a [4.4]cyclophane |
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| Authors: | Niculina D. Bogdan Eric Condamine Yvan Ramondenc Ion Grosu |
| Affiliation: | a Marie Curie Excellence Team, Dept. Chemie, LS AC Technische Universität München 4, Lichtenbergstrasse, 85747 Garching, Germany b Faculty of Chemistry and Chemical Engineering, ‘Babes-Bolyai’ University, 11 Arany Janos Street, 400028 Cluj-Napoca, Romania c IRCOF, UMR 6014, Faculté des Sciences, Université de Rouen, 76821 Mont Saint-Aignan, Cedex, France d Université de Rennes I, UMR 6251, 35042 Rennes, Cedex, France |
| Abstract: | The synthesis, the X-ray, NMR and molecular modeling structure determination of a new orthopara[4.4]cyclophane are reported. The similarity of the π(CO)-π(Ar) driven conformational equilibrium of this compound to the work of an amusement ride machinery is also revealed. |
| Keywords: | Molecular devices [4.4]Cyclophanes Dynamic NMR investigations X-ray structure Molecular modeling |
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