Nickel-catalyzed organozinc-induced unexpected 1,3-migration of tert-butyl from sulfur to carbon in N-tert-butanesulfinyl iminoacetates |
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| Authors: | Xun Sun Wei Zheng Bang-Guo Wei |
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| Affiliation: | a Department of Chemistry of Natural Drugs, School of Pharmacy, Fudan University, 138 Yixueyuan Road, Shanghai 200032, China
b Department of Chemistry, Fudan University, 220 Handan Road, Shanghai 200433, China |
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| Abstract: | The nickel-catalyzed reaction for an unexpected 1,3-migration of tert-butyl from sulfur to carbon, upon treatment of functionalized N-tert-butanesulfinyl iminoacetate in the presence of organozinc reagent, was developed. The generality has been explored by considering the flexibility in the structure of each reactive component, organozinc halide and N-tert-butanesulfinyl iminoacetate. |
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| Keywords: | 1,3-Migration Organozinc Ni(acac)2 N-sulfinylimines |
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