An in situ generated samarium complex as a practical catalyst for the efficient intramolecular hydroamination of non-activated alkenes |
| |
| Authors: | Coralie Quinet,Istvá n E. Markó |
| |
| Affiliation: | Université catholique de Louvain, Département de Chimie, Place Louis Pasteur 1, B-1348 Louvain-la-Neuve, Belgium |
| |
| Abstract: | Mixing SmI2 and NaN(TMS)2 generates in situ an efficient catalyst that promotes the intramolecular hydroamination of non-activated olefins. A wide range of aminoolefins can be cyclised smoothly using this simple protocol. Mechanistic studies led to the identification of the putative active catalyst. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
