Cycloaddition reactions of trimethylenemethane diyls generated from alkynyl iodonium salts |
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Authors: | Hee-Yoon Lee Yeokwon Yoon Yeon-Hee Lim Yonghan Lee |
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Institution: | School of Molecular Science (BK21) and Department of Chemistry, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 305-701, Republic of Korea |
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Abstract: | Intramolecular 2+3] cycloaddition reaction of trimethylenemethane diyls that were generated successfully from the reaction of malonate anions containing diene units with propynyl iodonium salts via alkylidene carbene intermediates produced linearly fused triquinanes. |
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Keywords: | Alkylidene carbene Trimethylenemethane Diyl Triquinane |
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