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Cycloaddition reactions of trimethylenemethane diyls generated from alkynyl iodonium salts
Authors:Hee-Yoon Lee  Yeokwon Yoon  Yeon-Hee Lim  Yonghan Lee
Institution:School of Molecular Science (BK21) and Department of Chemistry, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 305-701, Republic of Korea
Abstract:Intramolecular 2+3] cycloaddition reaction of trimethylenemethane diyls that were generated successfully from the reaction of malonate anions containing diene units with propynyl iodonium salts via alkylidene carbene intermediates produced linearly fused triquinanes.
Keywords:Alkylidene carbene  Trimethylenemethane  Diyl  Triquinane
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