Electrophilic (phenylsulfonyl)difluoromethylation of thiols with a hypervalent iodine(III)-CF2SO2Ph reagent |
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| Authors: | Wei Zhang |
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| Institution: | Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032, China |
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| Abstract: | A hypervalent iodine(III)-CF2SO2Ph compound (3) has been successfully prepared with selective nucleophilic reaction using PhSO2CF2SiMe3 reagent, and this previously unkown compound 3 was found to act as a new electrophilic (phenylsulfonyl)difluoromethylation reagent for a variety of S-nucleophiles under very mild reaction conditions. |
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| Keywords: | Fluorine Elctrophilic fluoroalkylation Hypervalent iodine compound |
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