Rhodium-catalyzed carbonylative [2+2+1] cycloaddition reactions: catalytic formation of bicyclic cyclohexenones [corrected |
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| Authors: | Lee Sang Ick Park Ji Hoon Chung Young Keun Lee Sueg-Geun |
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| Institution: | School of Chemistry and Center for Molecular Catalysis, Seoul National University, Seoul 151-747, Korea. |
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| Abstract: | The rhodium-catalyzed carbonylative 3+2+1] cycloaddition of trienes into bicyclohexenones has been developed. The carbonylated cycloaddition products have a high regioselectivity. This catalytic system tolerates functionalities including ether, sulfonamide, and ester. |
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