Room-temperature C-H arylation: merger of Pd-catalyzed C-H functionalization and visible-light photocatalysis |
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Authors: | Kalyani Dipannita McMurtrey Kate B Neufeldt Sharon R Sanford Melanie S |
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Affiliation: | Department of Chemistry, University of Michigan, 930 North University Avenue, Ann Arbor, Michigan 48109, USA. |
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Abstract: | This communication describes the development of a room-temperature ligand-directed C-H arylation reaction using aryldiazonium salts. This was achieved by the successful merger of palladium-catalyzed C-H functionalization and visible-light photoredox catalysis. The new method is general for a variety of directing groups and tolerates many common functional groups. |
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