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A Modified Glass Formation Criterion for Various Glass Forming Liquids with Higher Reliability
作者姓名:X.  H.  Du  J.  C.  Huang
作者单位:[1]Institute of Materials Science and Engineering, National Sun Yat-Sen University, Kaohsiung 804 [2]Department of Materials Engineering, Shenyang Institute of Aeronautical Engineering, Shenyang, 110034
基金项目:Supported by the National Science Council of Taiwan under Grant No 94-2216-E-110-010, and the Post-Doctoral Sponsorship from NSC under Grant No 95-2816-E-110-001.
摘    要:A modified indicator of the glass forming ability (GFA) from the previous 7 = Tx/(Tl + Tg) for various glass forming liquids is proposed based on a conceptual approach which combines more acceptable physical metallurgy views in terms of the time-temperature-transformation diagrams. It is found that the glass forming ability for glass forming liquids is closely associated mainly with two factors, i.e. (2Tx - Tg) and Tl (wherein Tx is the onset crystallization temperature, Tg the glass transition temperature, and Tl the liquidus temperature), and could be predicated by a unified parameter γm defined as (2Tx - Tg)/Tl. This approach is confirmed and validated by experimental data in various glass forming systems including oxide glasses, cryoprotectants and metallic glasses, which all shows a higher reliability when their glass forming ability is predicted by the modified parameter.

关 键 词:玻璃  成形能力  高稳定性  液态
收稿时间:2007-1-20
修稿时间:2007-01-20

A Modified Glass Formation Criterion for Various Glass Forming Liquids with Higher Reliability
X. H. Du J. C. Huang.A Modified Glass Formation Criterion for Various Glass Forming Liquids with Higher Reliability[J].Chinese Physics Letters,2007,24(5):1335-1338.
Authors:X H Du  J C Huang
Institution:Institute of Materials Science and Engineering, National Sun Yat-Sen University, Kaohsiung 804Department of Materials Engineering, Shenyang Institute of Aeronautical Engineering, Shenyang, 110034
Abstract:
Keywords:71  23  Cq  81  05  Kf
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