Mixed dimethyl sulfoxide-thiocarbamic ester complexes of platinum(II) halides |
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| Authors: | Giuseppina Faraglia Fiorenzo Barbaro Livia Sindellari |
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| Affiliation: | (1) Dipartimento di Chimica Inorganica, Metallorganica ed Analitica dell'Università, via Loredan 4, Padova, Italy |
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| Abstract: | Summary The platinum(II) halidecis-[Pt(DMTC)(DMSO)X2] andcis-[Pt(DETC)(DMSO)X2](X=Cl or Br; DMSO=dimethyl sulfoxide; DMTC=EtOSCN-Me2; DETC=EtOSCNEt2) adducts and the platinum(II) and palladium(II) halide adducts,trans-[M(DETC)2X2] (M=Pt or Pd; X=Cl or Br), have been prepared. The complexes were characterized by i.r., and1H and13Cn.m.r. spectroscopy. Both DMTC and DETC coordinate through the sulphur atoms. The 1:2 DETC complexes present the usualtrans configuration, whereas the presence of DMSO favourscis geometry in the mixed species. |
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